Technology Information

Organic Semiconductor Structure Providing Efficient Intermolecular Interactions Among the Pi-electrons

Organic semiconductor building blocks are co-crystalized with the functional groups that reinforce stacking through H-bond interactions.
UIRF Case #:06035


Relevant PublicationsLevel of Development
Technology DescriptionInventor Web Site Link
Patent LinksContact Information
Other Information 

Relevant Publications

Sokolov AN, Frisić T, MacGillivray LR. Enforced face-to-face stacking of organic semiconductor building blocks within hydrogen-bonded molecular cocrystals. J. Am. Chem. Soc., 2006; 128 (9): 2806�2807.
Link

Level of Development

General: Experimental Proof of Concept

Technology Description

Researchers at University of Iowa have developed a solid phase semiconductive organic polymer structure that improves face-to-face stacking of monomers, hence providing the backbone structure for much more efficient intermolecular electron transfers. Aromatic molecules, such as thiophene based compounds, have rich electron centers (face) comprised of the network of pi-electrons and are commonly used as the "building blocks" of conductive/semiconductive organic polymers. The inventors of this technology have created the modified thiophene and anthracene compounds by co-crystallizing them with the anchoring functional groups that reinforce the molecular alignment (stacking) of building blocks through the hydrogen-bonding interactions rather than through already-reported dipole-dipole or van der Waals interactions. This structure provides a much more rigid construct for the overlapping orbital of pi-electrons which improves the efficiency of intermolecular electron mobility among the stacked individual building blocks.

Inventor Web Site Link(s)

http://www.chem.uiowa.edu/people/leonard-r-macgillivray

Patent Link(s)

US7524373    US8328933    

Contact Information

Sean Kim
hyeon-kim@uiowa.edu
319-335-4607

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